BTW, poly does indeed "bite" the ball more. This is because poly is so stiff, it makes for a stiffer, less resilient stringbed which gives less on ball impact. When the ball collides with the stringbed, something has to give, and since the stringbed is so unyielding, the ball has to compress or "flatten" more on the stringbed because that energy has to go somewhere. When this happens, a greater percentage of the fuzzy outer surface area of the ball makes contact with more of the strings on the stringbed. This allows more strings to grab or "bite" the ball as you brush up on the back of the ball. More strings to add rotational force to a greater surface area of the ball. This is one reason why poly gives more spin. This is also why when you hit the ball hard with poly, the "pop" sound is louder than with other softer strings. That's the sound of the ball compressing (flattening) more against the stringbed.
The other reason for poly giving more spin is again its low resiliency and stiffness but in the lateral direction. It resists moving aside large distances better than more resilient strings do. Polys may be slippery when new, but since they don't stretch as much, the ball cannot push it aside as much during impact before it stops stretching/moving and "catches" or stops the ball so it can start imparting spin on it with your upward swing.
Polys may be less comfortable when old and less slippery because they don't slide or "give" as easily both in the normal direction and laterally. And since the strings don't "give" as much when you brush up on it, you'll likely feel the stiffness and low resiliency of the strings more, thereby, making it feel "harsher" or "dead".