If there was a change from a 90 degree angle, to an 45 degree angle, it does not occur during contact at all. Its important to keep in mind that there is no "snap" during the contact. The arm should be relaxed and the grip pressure as light as possible, but for the most part the wrist is essentially along for the ride. Any forward movement, if and when it does occur, is a natural consequence of the swing. Focusing on using or worse snapping the wrist is "counterproductive in generating power or spin" according to John Yandell.
Sometimes the amount of layback, and therefore the angle between the racket and the forearm, decreases as the racket comes forward to the ball (which is often described as a wrist release). When this movement does happen, it seems obvious that it is a natural consequence of the swing--and the fact that the players are staying as relaxed as possible.
If there were a conscious "snap" or muscle contraction coinciding with the hit, we would see the angle between the racket and the forearm changing radically just before and after contact. If you think about, if a player really snapped his wrist all the way forward at contact, it would send the ball into the left side fence. In the hundreds of forehand video clips out there, the wrist remained substantially laid back both before and after contact. In fact, we sometimes see the laid back angle actually increase slightly after contact due to the impact of the ball. Again this is due to relaxation in the hitting arm.
The high speed video also shows that the top players maintain the hitting arm position, keeping the wrist back, until the racket and racket hand are well out past the contact. Typically, this appears to be around two feet or so into the followthrough. Only after reaching this point does the hitting arm clearly start to lose its characteristic shape. Here I personally think the real wrist release occurs. At this point the ball has been off the strings for a significant amount of time.