Without a closeup view, it's difficult to be certain; however, it appears that tie-off grommet 6B on the left side is split or torn and has sharp edges. I wouldn't be surprised if this cut through the body of the knot and caused breakage. The remaining knots all appear to have the proper Parnell shape, so you clearly know how to tie them properly. Inspect the grommet and let us know what you find.