Pressureless balls have thicker rubber than pressurized balls, but they weigh about the same. This means that the pressureless balls have lower moment of inertia.
The lower moment of inertia causes the spin rate to slow down more as the ball travels through the air. So the spin you put on the ball will have less effect. To some people, this gives them the sensation of hitting rocks because rocks don't curve much in the air either.
The bottom line is that pressureless balls will feel good if you are someone who uses little or no topspin, and you almost always hit flat or with slice. If you like to put an appreciable amount of topspin on your shots, you will probably hate pressureless balls, since they won't bend in the air much, and your topspin shots will bounce much lower.