This thread has accomplished nothing in terms of better understanding of performance/spin from polys. What is has accomplished is greater confusion and more experimentation from my end!
http://twu.tennis-warehouse.com/learning_center/COFreporter.php
check out that link. The reports at the top of the page go into spin production in relation to the different types of string materials, textures and friction.
The more important report is here:
http://twu.tennis-warehouse.com/learning_center/slidingCOF.php
This lays out for you very simply that spin production is maximized not by texture, but by sliding coefficient of friction.
Textured strings increase spin for players who rely on ball to string friction. These are players with slow swing speeds and lightweight racquets.
Smooth, unshaped poly strings that are very slick, strung in both mains and crosses produce the most spin for people with faster swing speeds -- in other words, people that aren't relying on ball to string friction. Players that fit into this category are producing spin through the ball impact on the string bed: the ball moves and separates both the mains AND crosses during dwell-time.
As the dwell-time finishes and the ball begins to leave the string bed, the mains and cross strings slide over each other to go back to their initial positions, before the ball hit the string bed. This "snap-back" actually grabs onto the ball and spins the ball, producing far more spin than merely "ball to string" friction can allow.
Let's also not forget that even in the above example, there IS still ball to string friction. Even though the poly is technically smooth, it is still producing spin in that way too.
Last but not least, the third and final factor in spin production is technique. Proper swing path, weight transfer and racquet head speed also assist in spin production.
If you can get all three of those factors with a full bed of smooth polyester string, you will be producing more spin on the ball than with any other type of string, hands down.