In NO way can a winning % on grass be a good predictor because you don't know what it is until Wimbledon is over. You don't know much after a grass tune-up, and players don't necessarily even do that now.
You also can't go by who has the highest %, because in some cases you end up with a tune-up result before a player is out in a very early round. So there is simply not enough data.
However, you can surmise after the fact that the most dominant grass players, the ones who win several Wimbledons and who are also ranked at #1 or very close to it, will be close to 60% or over that mark, year after year, and you can see that the result in Wimbledon itself is a huge indicator of the whole season today because it is MOST of the season.
If a champion wins a tune-up, 5 matches Bo3, then Wimbledon, 7 matches, Bo5, most of the record will be from the slam itself.
Then you look at who has won Wimbledon and who won it with more than 60% of games, and mostly you find the best of the best at the top of that list.
In fact, if you look at all 53 entries here:
http://tennis28.com/slams/games_winpct_tournament.html#low_winner
You pretty much find the names of the greatest players, and most of the time the people listed there won those slams, all those marked *.
So saying there is a high correlation between % of games won BEFORE slams and predicting who is most likely to win those slams is pretty high, and it works best for HCs because so many games are played before the USO, and you can make a good prediction by watching what happens between the USO and the beginning of the next year.
At the time of the USO Fed and Novak were almost exactly even, with Fed actually a bit ahead. That's why I figured he had a good chance at the USO. Since then he has moved down just a little, and Novak has been moving up a bit. So it's not exactly rocket science to say:
1) He is the most likely to win the AO.
2) If his record stays this high, still over 60% by the USO, he is very likely to win that too.
3) You can't ever predict someone like Cilic or Waw.
The biggest mystery to me is that Sampras never had a slam where he won 65%, and he appears twice on the this list:
http://tennis28.com/slams/games_winpct_tournament.html#low_winner
According to my own research Pete of all the champions I've studied coasted more than anyone else. You either have to assume that he was in the weakest era ever - which I do NOT believe - or that Pete had an extra gear that no one else in the Open Era had - and that I DO believe.